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Professor Scott Eric Denmark
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Publications

Allylmetal Aldehyde and Acetal Reactions

  1. On the Stereochemistry of Allylmetal-Aldehyde Condensations (with E. J. Weber) Helv. Chim. Acta 1983, 66, 1655-1660. [pdf]
     
  2. Stereochemistry of Allylmetal-Aldehyde Condensations. 2. Allylstannanes (with E. J. Weber) J. Am. Chem. Soc. 1984, 106, 7970-7971. [pdf]
     
  3. SnCl 4(4-t-BuC 6H 4CHO) 2. X-Ray Crystal Structure, Solution NMR, and Implications for Reactions at Complexed Carbonyls (with B. R. Henke and E. J. Weber) J. Am. Chem. Soc. 1987, 109, 2512-2514. [pdf]
     
  4. On the Lewis-Acid Induced Addition of Allylstannanes to Aldehydes: A Spectroscopic Investigation (with T. Wilson and T. M. Willson) J. Am. Chem. Soc. 1988, 110, 984-986. [pdf]
     
  5. Stereochemical and Spectroscopic Studies on the Reaction of Allylstannanes with Aldehydes (with E. J. Weber, T. M. Wilson and T. M. Willson) Tetrahedron1989, 45, 1053-1065. [pdf]
     
  6. Mechanistic and Stereochemical Divergence in the Allylsilane-Acetal Addition Reaction (with T. M. Willson) J. Am. Chem. Soc. 1989, 111, 3475-3476. [pdf]
     
  7. Studies of the Mechanism of Allylmetal-Acetal Additions (with T. M. Willson) In Selectivity in Lewis Acid Promoted Reactions; Schinzer, D. Ed.; D. Reidel: Amsterdam, 1989; pp 247-263. [pdf]
     
  8. The Origin of Stereoselective Opening of Chiral Dioxane and Dioxolane Acetals: The Solution Structure of Their Lewis Acid Complexes (with T. M. Willson and N. G. Almstead) J. Am. Chem. Soc. 1989, 111, 9258-9260. [pdf]
     
  9. Studies on the Mechanism and Origin of Stereoselective Opening of Chiral Dioxane Acetals (with N. G. Almstead) J. Am. Chem. Soc. 1991, 113, 8089-8110. [pdf]
     
  10. On the Stereoselective Opening of Achiral Dioxane Acetals (with N. G. Almstead) J. Org. Chem. 1991, 56, 6458-6467. [pdf]
     
  11. On the Stereoselective Opening of Chiral Dioxane Acetals. Nucleophile Dependence (with N. G. Almstead) J. Org. Chem. 1991, 56, 6585-6587. [pdf]
     
  12. Spectroscopic Studies on the TiCl, 4-Promoted Reaction of Allylsilanes with Aldehydes and a, B -Enones (with N. G. Almstead) Tetrahedron, 1992, 46, 5565-5578. [pdf]
     
  13. Spectroscopic Studies on the Structure of Lewis Acid - Aldehyde Complexes (with N. G. Almstead) J. Am. Chem. Soc. 1993, 115, 3133-3139. [pdf]
     
  14. Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The S E Component (with N. G. Almstead) J. Org. Chem. 1994, 59, 5130-5132. [pdf]
     
  15. Stereochemical Studies on the Addition of Allylstannanes to Aldehydes. The S E' Component (with S. Hosoi) J. Org. Chem. 1994, 59, 5133-5135. [pdf]
     
  16. Asymmetric Allylation of Aldehydes with Chiral Lewis Bases (with D. M. Coe, N. E. Pratt, and B. D. Griedel), J. Org. Chem. 1994, 59, 6161-6163. [pdf]
     
  17. On the Mechanism of Catalytic, Enantioselective Allylation of Aldehydes with Chlorosilanes and Chiral Lewis Bases (with J. Fu) J. Am. Chem. Soc. 2000, 122, 12021-12022. [pdf]
     
  18. Lewis Base Activation of Lewis Acids: Catalytic Enantioselective Allylation and Propargylation of Aldehydes (with T. Wynn) J. Am. Chem. Soc. 2001, 123, 6199-6200. [pdf]
     
  19. Catalytic, Enantioselective Addition of Substituted Allylic Trichlorosilanes Using a Rationally-Designed 2,2'-Bispyrrolidine-Based Bisphosphoramide (with J. Fu) J. Am. Chem. Soc. 2001, 123, 9488-9489. [pdf]
     
  20. Asymmetric Construction of Quaternary Centers by Enantioselective Allylation: Application to the Synthesis of the Serotonin Antagonist LY426965 (with J. Fu) Org. Lett. 2002, 4, 1951-1953. [pdf]
     
  21. Catalytic Enantioselective Allylation with Chiral Lewis Bases (with J. Fu) Chem. Commun. 2003, 167-170. [pdf]
     
  22. Understanding the Correlation of Structure and Selectivity in the Chiral-Phosphoramide-Catalyzed Enantioselective Allylation Reactions: Solution and Solid-State Structural Studies of Bisphosphoramide ·SnCl 4 Complexes (with J. Fu) J. Am. Chem. Soc. 2003, 125, 2208-2216. [pdf]
     
  23. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones, (with J. Fu) Chem. Rev. 2003, 103, 2763-2793. [pdf]
     
  24. Chiral Phosphoramide-Catalyzed Enantioselective Addition of Allylic Trichlorosilanes to Aldehydes. Preparative Studies with Bidentate Phosphorus-Based Amides (with J. Fu, and M. J. Lawler) J. Org. Chem.2006, 71, 1523-1536. [pdf]
     
  25. Chiral Phosphoramide-Catalyzed Enantioselective Addition of Allylic Trichlorosilanes to Aldehydes. Preparative and Mechanistic Studies with Monodentate Phosphorus-Based Amides (with J. Fu, D. M. Coe, X. Su, N. E. Pratt, and B. D. Griedel) J. Org. Chem.2006, 71, 1513-1522. [pdf]

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