Professor | Scott Eric Denmark

> Chemistry at Illinois

Department of Chemistry, UIUC

Miscellaneous

An Ab Initio Study of the [1,2] Proton Transfer from Phosphine Oxide to Phosphinic Acid (with C. J. Cramer and C. E. Dykstra) Chem. Phys. Lett. 1987, 136, 17-21. [pdf]
The Stereochemical Course of Migration from Phosphorus to Nitrogen in the Photo-Curtius Rearrangement of Phosphinic Azides (Harger Reaction) (with R. L. Dorow) J. Org. Chem. 1989, 54, 5-6. [pdf]
The Vinylogous Anomeric Effect in 3-Chloro-2-alkylcyclohexanone Oximes and Oxime Ethers (with R. T. Jacobs, M. S. Dappen and N. L. Sear) J. Am. Chem. Soc. 1990, 112, 3466-3474. [pdf]
Synthesis, Structure and Reactivity of an Organogermanium Lewis Acid (with R. T. Jacobs, G. Dai-Ho and S. Wilson) Organometallics 1990, 9, 3015-3019. [pdf]
Synthesis of alpha- and beta-Branched Ethers from Alcohols by the Reaction of Acetals with Grignard Reagents: Synthesis of Isopropyl and Isobutyl Ethers of (1S,2RS,4R),-6-Methylenebicyclo [2.2.2]octan-2-ol (with T. M. Willson and J. Amburgey) J. Chem. Soc., Perkin Trans. 1 1991, 2899-2906. [pdf]
Preparation of Chiral Bisoxazolines: Observations on the Effect of Substituents (with N. Nakajima, O. J.-C. Nicaise, A.-M. Faucher and J. P. Edwards) J. Org. Chem. 1995, 60, 4884-4892. [pdf]
(R)-(–)-2,2-Diphenylcyclopentanol (with L. R. Marcin, M. E. Schnute and A Thorarensen) Org. Synth. 1996,74, 33-49. [pdf]
Synthesis of Phosphoramides for the Lewis Base-catalyzed Allylation and Aldol Addition Reactions (with X. Su, Y. Nishigaichi, K.-T. Wong, D. M. Coe, S. B. D. Winter and J.-Y. Choi) J. Org. Chem. 1999, 64, 1958-1967. [pdf]
Stereospecific Cleavage of Carbon-Phosphorus Bonds: Stereochemical Course of the Phosphinoyl Curtius (Harger) Reaction (with R. L. Dorow) Chirality 2002, 14, 241-257. [pdf]
(R,R)-2,2'-Bispyrrolidine and (S,S)-2,2'-Bispyrrolidine (with J. Fu and M. J. Lawler) Org. Synth. 2006, 83, 121-130. [pdf]
On the Mechanism of the Skraup-Doebner-Von Miller Quinoline Synthesis (with S. Venkatraman) J. Org. Chem.2006, 71, 1668-1676. [pdf]
Preparation of chiral bipyridine bis-N-oxides by oxidative dimerization of chiral pyridine N-oxides (with Y. Fan) Tetrahedron: Asymmetry 2006, 17, 687-707. [pdf]

Neutral and Cationic Phosphoramide Adducts of Silicon Tetrachloride: Synthesis and Characterization of Their Solution and Solid-State Structures (with B. M. Eklov) Chem. Eur. J. 2008, 14, 234-239. [pdf]

Lewis Base Catalysis in Organic Synthesis (with G. L. Beutner) Angew. Chem. Int. Ed. 2008, 47, 1560-1638. [pdf]

Asymmetric Catalysis with Chiral Lewis Bases: A New Frontier in Main Group Chemistry Chimia 2008, 62, 37-40. [pdf]

1,5-Pentanediamine, N,N'-bis[(11bR)-3,5-dihydro-3,5-dimethyl-4-oxido-4H-dinaphtho[2,1-d:1',2'-f][1,3,2]diazaphosphepin-4-yl]-N,N'-dimethyl (with J. R. Heemstra, Jr.) e-EROS Encyclopedia of Reagents for Organic Synthesis [DOI: 10.1002/047084289X.rn00771] 2008. [pdf]

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