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Professor Scott Eric Denmark
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Publications

Chemistry of Phosphorus-Stabilized Anions

  1. The Solution and Solid State Structure of a Phosphorus-Stabilized Carbanion (with R. L. Dorow) J. Am. Chem. Soc. 1990, 112, 864-866.[pdf]
     
  2. The Theoretical Structures of Neutral, Anionic and Lithiated P-Allylphosphonic Diamide (with C. J. Cramer) J. Org. Chem. 1990, 55, 1806-1813.[pdf]
     
  3. Stereoselective Alkylations of Chiral, Phosphorus-Stabilized Benzylic Carbanions (with R. L. Dorow) J. Org. Chem. 1990, 55, 5926-5928.[pdf]
     
  4. The Configuration and Conformation and Colligative Properties of a Phosphorus-Stabilized Anion (with P. C. Miller and S. R. Wilson) J. Am. Chem. Soc. 1991, 113, 1468-1470.[pdf]
     
  5. Asymmetric Electrophilic Amination of Chiral Phosphorus-Stabilized Anions (with N. Chatani and S. V. Pansare) Tetrahedron1992, 48, 2191-2208.[pdf]
     
  6. Electrophilic Activation of the Horner-Wadsworth-Emmons-Wittig Reaction: Highly Selective Synthesis of Dissymmetric Olefins (with C.-T. Chen) J. Am. Chem. Soc. 1992, 114, 10674-10676.[pdf]
     
  7. Solution and Solid-State Structure, and Dynamics of Thiophosphonamide Anions: Electronic Tuning of Rotational Barriers (with K. A. Swiss and S. R. Wilson) J. Am. Chem. Soc. 1993, 115, 3826-3827.[pdf]
     
  8. A New, General and Stereoselective Method for the Synthesis of Trisubstituted Alkenes (with J. Amburgey) J. Am. Chem. Soc. 1993, 115, 10386-10387.[pdf]
     
  9. On the Carbanion Hybridization of Thiophosphonamide-Stabilized Anions: Remarkable Steric and Solvation Effects (with K. A. Swiss) J. Am. Chem. Soc. 1993, 115, 12195-12196.[pdf]
     
  10. Structure and Dynamics of Phosphorus(V)-Stabilized Carbanions: A Comparison of Theoretical, Crystallographic, and Solution Structures (with C. J. Cramer, P. C. Miller, R. L. Dorow, K. A. Swiss and S. R. Wilson) J. Am. Chem. Soc. 1994, 116, 2437-2448.[pdf]
     
  11. Alkylation of Chiral, Phosphorus-Stabilized Carbanions: Substituents Effects on the Alkylation Selectivity (with C.-T. Chen) J. Org. Chem. 1994, 59, 2922-2924.[pdf]
     
  12. Asymmetric Carboalkoxyalkylidenation with a Chiral Horner-Wadsworth-Emmons Reagent (with I. Rivera) J. Org. Chem. 1994,59, 6887-6889.[pdf]
     
  13. Enantioselective Synthesis of Alkylidene Cyclohexanes by an Asymmetric Olefination / Cross Coupling Sequence (with C.-T. Chen) Heteroatom Chemistry 1995, 6, 133-144.[pdf]
     
  14. An Ab Initio Study of the P-C Bond Rotation in Phosphorus-Stabilized Carbanions: The Phosphoryl versus the Thiophosphoryl Group (with M. Kranz) J. Org. Chem. 1995, 60, 5867-5877.[pdf]
     
  15. Asymmetric [2,3]-Wittig Rearrangements with Chiral, Phosphorus Anion-Stabilizing Groups (with P. C. Miller) Tetrahedron Lett. 1995, 36, 6631-6634.[pdf]
     
  16. An Asymmetric Michael Addition Reaction of Phosphorus-Stabilized Allyl Anions with Cyclic Enones (with J.-H. Kim) J. Org. Chem. 1995, 60, 7535-7547.[pdf]
     
  17. Alkylations of Chiral, Phosphoryl- and Thiophosphoryl-Stabilized Carbanions (with C.-T. Chen) J. Am. Chem. Soc. 1995, 117, 11879-11897. [pdf]
     
  18. Solution and Solid-State Structure of a Lithiated Phosphine Oxide (with K. A. Swiss and S. R. Wilson) Angew. Chem., Int. Ed. Engl. 1996, 35, 2515-2517 (German version, Angew. Chem. 1996, 108, 2686-2688).[pdf]
     
  19. An Ab initio Study of the P-C Bond Rotation in Phosphoryl- and Thiophosphoryl-Stabilized Carbanions: Five- and Six-membered Heterocycles (with M. Kranz, K. A. Swiss, and S. R. Wilson) J. Org. Chem. 1996, 61, 8551-8563.[pdf]
     
  20. Solution and Solid-State Structure of Lithiated Cyclic Phosphonates (with K. A. Swiss, P. C. Miller and S. R. Wilson) Heteroatom 1998, 9, 209-218.[pdf]
     
  21. Diastereoselective Alkylations of Chiral, Phosphorus-Stabilized Carbanions: N-Alkyl Substituent Effects in P-Alkyl-1,3,2-diazaphosphorinanes (with J.-H. Kim) Can. J. Chem. 2000, 78, 673-688.[pdf]
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