2006-2007

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147. Jayaraman,S.; Gerbi, J.E.; Yang, Y.; Kim, D. Y.; Chatterjee, A.; Bellon, P.; Girolami, G. S.; Chevalier, J.-P.; Abelson, J. R. "HfB2 and Hf-B-N Hard Coatings by Chemical Vapor Deposition," Surf. Coatings Technol. 2006, 200, 6629. Link to pdf.

148. Goedde, D. M.; Girolami, G. S. "Titanium(II) and Titanium(III) Tetrahydroborates. Crystal Structures of [Li(Et2O) 2][Ti2(BH4)5(PMe2Ph)4], Ti(BH4)3 (PMe2Ph)2, and Ti(BH4)3(PEt3)2," Inorg. Chem. 2006, 45, 1380. Link to pdf.

149. Yang, Y.; Jayaraman, S.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "Crystalline Texture in Hafnium Diboride Thin Films Grown by Chemical Vapor Deposition," J. Cryst. Growth 2006, 294, 389. Link to pdf.

150. Dickinson, P. W.; Girolami, G. S. "Synthesis, Characterization, and X-ray Crystal Structure of the Octabromodiosmate(III) Salt [(C5Me4H)2OsBr]2[Os2Br8] and its Conversion to [(C5Me 4H)2OsBr]­[Os2HBr4(cod)2]," J. Organomet. Chem. 2006, 691, 2883. Link to pdf.

151. Dickinson, P. W.; Girolami, G. S. "Synthesis and Characterization of Osmium(II) Trispyrazolylborate Complexes," Inorg. Chem. 2006, 45, 5215. Link to pdf.

152. Yang, Y.; Jayaraman, S.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "CVD Growth Kinetics of HfB2 Thin Films from the Single Source Precursor Hf(BH4)4," Chem. Mater. 2006, 18, 5088. Link to pdf.

153. Brumaghim, J. L.; Gross, C. L.; Girolami, G. S. "Synthesis, Characterization, and Crystal Structures of the Osmium Triflate Complexes Cp*Os(P-P)(OTf) and [Cp*Os(P-P)(OH2)][OTf]," J. Organomet. Chem. 2006, 691, 3874. Link to pdf.

154. Kim, D. Y.; Girolami, G. S. "Synthesis and Characterization of the Octahydrotriborate Complexes Cp*V(B3 H8)2 and Cp*Cr(B3H8)2, and the Unusual Cobaltaborane Cluster Cp* 2Co2(B6H14)," J. Am. Chem. Soc. 2006, 128, 10969. Link to pdf.

155. Gross, C. L.; Girolami, G. S. "Synthesis and Characterization of Osmium(IV) Polyhydride Complexes of Stoichiometry (C5 Me5)OsH3(L). Crystal Structures of (C5Me5)OsH3(AsPh3) and ( C5Me5)OsH3(PPh3)," Organometallics 2006, 25, 4792. Link to pdf.

156. Noh, W. T.; Girolami, G. S. "Rhenium Oxohalides. Synthesis and Crystal Structures of ReO3Cl(THF)2, ReOCl4(THF), Re2O3Cl6(THF)2, and Re2O3Cl 6(H2O)2," Dalton Trans. 2007, 674. Link to pdf.

157. Yang, Y.; Jayaraman, S.; Sperling, B.; Kim, D. Y.; Girolami, G. S.; Abelson, J. R. "In-Situ Spectroscopic Ellipsometry Analyses of Hafnium Diboride Thin Films Deposited by Single-Source Chemical Vapor Deposition," J. Vac. Sci. Tech. A 2007, 25, 200. Link to pdf.

158. Holmes, S. M.; Whelpley, A. S.; Girolami, G. S. "Nanocomposite of a Chromium Prussian Blue with TiO2. Redox Reactions and the Synthesis of Prussian Blue Molecule-Based Magnets," Polyhedron 2007, 26, 2291. Link to pdf.

159. Gross, C. L.; Girolami, G. S. "Synthesis and Characterization of Osmium Polyhydrides. X-ray Crystal Structures of (C5Me 5)OsH5 and (C5Me5)2Os2H4," Organometallics 2007, 26, 160. Link to pdf.

160. Spencer, M. D.; Shelby, Q. D.; Girolami, G. S. "Titanium-Catalyzed Dehydrocoupling of Silanes: Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Si-H•••Ti Interactions," J. Am. Chem. Soc. 2007, 129, 1860. Link to pdf.

161. Gross, C. L.; Brumaghim, J. L.; Girolami, G. S. "Synthesis and Reactivity of the Osmium(III) Pentamethylcyclopentadienyl Complex (C5Me5)2Os2Br4. X-ray Crystal Structures of (C5Me5) 2Os2Br4, (C5Me5)2Os2(μ-O)Br4, and (C5Me5)2Os2(μ-NPh)2Br2," Organometallics 2007, 26, 2258. Link to pdf.

162. Gross, C. L.; Girolami, G. S. "Synthesis and NMR Studies of [(C5Me5)Os(L)H2(H2) +] Complexes. Evidence of the Adoption of Different Structures by a Dihydrogen Complex in Solution and the Solid State," Organometallics 2007, 26, 1658. Link to pdf.

163. Harada, Y.; Girolami, G. S. "Synthesis and Crystal Structures of the Chromium(II) and Chromium(III) Hexafluoroacetylacetonate Complexes trans-Cr(hfac)2(thf)2 and Cr(hfac)3," Polyhedron 2007, 26, 1758. Link to pdf.

164. Goedde, D. M.; Windler, G. K.; Girolami, G. S. "Synthesis and Characterization of the Homoleptic Octahydrotriborate Complex Cr(B3H8)2 and its Lewis Base Adducts," Inorg. Chem. 2007, 46, 2814. Link to pdf.

165. Noh, W. T.; Girolami, G. S. "X-ray Crystal Structure of the Tetra(tert-butyl)erbate Anion and Attempts to Prepare Tetravalent Organolanthanide Complexes," Polyhedron 2007, 26, 3865. Link to pdf.

166. Kumar, N.; Yang, Y.; Noh, W. T.; Girolami, G. S.; Abelson, J. R. "Titanium Diboride Thin Films By Low Temperature Chemical Vapor Deposition from the Single Source Precursor Ti(BH4)3(1,2 Dimethoxyethane)," Chem. Mater. 2007, 19, 3802. Link to pdf.

167. Lazarz, T. S.; Yang, Y.; Kumar, N.; Kim, D. Y.; Noh, W.; Girolami, G. S.; Abelson, J. R. "Low Temperature CVD of Ru from C6H8Ru(CO)3," Mater. Res. Soc. Symp. Proc. 2007, 990, 103.

168. Kim, D. Y.; Yang, Y.; Abelson, J. R.; Girolami, G. S. "Volatile Magnesium Octahydrotriborate Complexes as Potential CVD Precursors to MgB2. Synthesis and Characterization of Mg(B3H8)2 and its Etherates," Inorg. Chem. 2007, 46, 9060. Link to pdf.

169. Noh, W.; Girolami, G. S. "Synthesis and Characterization of the Cycloheptatrienyl Tantalum Mixed Sandwich Compounds (C5 R5)Ta(C7H7)," Inorg. Chem. 2008, 47, 535. Link to pdf.

170. Jeffries, P. M.; Ellenwood, R. E.; Girolami, G. S. "Anionic Ruthenium(II) Alkyls with Ancillary Diene and Dienyl Ligands: Synthesis and Structures of [(η22-C7H8)RuMe4]2- and [(η 32-C8H11)RuMe3]2-," Inorg, Chim. Acta, in press.

171. Morse, P. M.; Shelby, Q. D.; Kim, D. Y.; Girolami. G. S. "Ethylene Complexes of the Early Transition Metals. Crystal Structures of [HfEt4(C2H4)2-] and the Negative Oxidation State Species [TaHEt(C2H4) 33-] and [WH(C2H4)43-]," Organometallics, in press. Link to pdf.

172. Kim, D. Y.; You, Y.; Girolami, G. S. "Synthesis and Crystal Structures of Two (Cyclopentadienyl)titanium(III) Hydroborate Complexes, [Cp*TiCl(BH4)]2 and Cp2Ti(B3H8)," J. Organomet. Chem., in press.

173. You, Y.; Wilson, S. R.; Girolami, G. S. "Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Oligomerization Catalysis," Organometallics, submitted.

174. Gross, C. L.; Brumaghim, J. L.; Jefferis, J. M.; Dickinson, P. W."Mono(pentamethylcyclopentadienyl) Complexes of Osmium," Inorg. Synth., accepted.


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