Pouy, M. J; Stanley, L. M.; Hartwig, J. F.Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia. J. Am. Chem. Soc. 2009, ASAP. [doi]
Vo, G. D.; Hartwig, J. F. Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. J. Am. Chem. Soc. 2009, ASAP. [doi]
Weix, D. J.; Markovic, D.; Ueda, M.; Hartwig, J. F. Direct, Intermolecular, Enantioselective, Iridium-Catalyzed Allylation of Carbamates to Form Carbamate-Protected, Branched Allylic Amines. Org. Lett. 2009, 11, 2944–2947. [doi]
Stanley, L. M.; Hartwig, J. F. Regio- and Enantioselective N-Allylations of Imidazole, Benzimidazole, and Purine Heterocycles Catalyzed by Single-Component Metallacyclic Iridium Complexes. J. Am. Chem. Soc. 2009, 131, 8971–8983. [doi]
Alvaro, E.; Hartwig, J. F. Resting State and Elementary Steps of the Coupling of Aryl Halides with Thiols Catalyzed by Alkylbisphosphine Complexes of Palladium. J. Am. Chem. Soc. 2009, 131, 7858-7868. [doi]
Barrios-Landeros, F.; Carrow, B. P.; Hartwig, J. F.Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes. J. Am. Chem. Soc. 2009, 131, 8141-8154. [doi]
Madrahimov, S.T.; Markovic, D.; Hartwig, J .F. The Allyl Intermediate in Regioselective and Enantioselective Iridium-Catalyzed Asymmetric Allylic Substitution Reaction. J. Am. Chem. Soc. 2009, 131, 7228-7229. [doi]
Fernández-Rodríguez, M.A.; Hartwig, J.F. A General, Efficient, and Functional-Group-Tolerant Catalyst System for the Palladium-Catalyzed Thioetherification of Aryl Bromides and Iodides J. Org. Chem. 2009, 1663-1672. [doi]
Zhou, J.; Hartwig, J.F. Iridium-Catalyzed H/D Exchange at Vinyl Groups without Olefin Isomerization Angew. Chem. Int. Ed. 2008, 47, 5783-5787. [doi]
Hartwig, J.F. Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides Acc. Chem. Res.2008, 41, 1534-1544. [doi]
Hartwig, J.F. Carbon–Heteroatom Bond Formation Catalysed by Organometallic Complexes Nature 2008, 455, 314-322. [full text]
Boebel, T.A.; Hartwig, J.F. Conversion of 1,3-Disubstituted Arenes to Chiral α,α-Diaryl Methylammonium Chlorides Using Arene Borylation Tetrahedron 2008, 64, 6824-6830. [doi]
Boebel, T.A.; Hartwig, J.F. Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes Organometallics 2008, 27, 6013-6019. [doi]
Herzon, S.B.; Hartwig, J.F. Hydroaminoalkylation of Unactivated Olefins with Dialkylamines J. Am. Chem. Soc. 2008, 130, 14940–14941. [doi]
Alexanian, E.J.; Hartwig, J.F. Mechanistic Study of β-Hydrogen Elimination from Organoplatinum(II) Enolate Complexes J. Am. Chem. Soc. 2008, 130, 15627-15635. [doi]
Ogata, T.; Hartwig, J.F. Palladium-Catalyzed Amination of Aryl and Heteroaryl Tosylates at Room Temperature J. Am. Chem. Soc. (Communication) 2008, 130, 13848-13849. [doi]
Zhou, J. and J. F. Hartwig Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity. J. Am. Chem. Soc. 2008, 130, 12220-12221. [doi]
Zhao, P. and J. F. Hartwig Insertions of Ketones and Nitriles into Organorhodium(I) Complexes and b-Hydrocarbyl Eliminations from Rhodium(I) Alkoxo and Iminyl Complexes. Organometallics 2008, 27, 4749-4757. [doi]
Shen, Q. and J. F. Hartwig [(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides. Org. Lett. 2008, 18, 4109-4112. [doi]
Tye, J. W., Weng, Z., Johns, A. M., Incarvito, C. D., and J. F. Hartwig Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides. J. Am. Chem. Soc. 2008 130(330) p. 9971-9983. [doi]
Liao, X., Weng, Z., and J. F. Hartwig, Enantioselective-Arylation of Ketones with Aryl Triflates Catalyzed by Difluorphos Complexes of Palladium and Nickel. J. Am. Chem. Soc. 2008 130(1) p. 195-200. [doi]
Liu, Z., and J. F. Hartwig, Mild, Rhodium-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Olefins with Primary and Secondary Amines. J. Am. Chem. Soc. 2008 130(5) p. 1570-1571. [doi]
Ueno, S., and J. F. Hartwig, Direct, Iridium-Catalyzed Asymmetric Allylic Etherification with Aliphatic Alcohols. Angew. Chem. Int. Ed. 2008 47(10) p. 1928-1931. [doi]
Vo, G.D., and J. F. Hartwig, Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [Pd(allyl)Cl]2 and DPPF or Q-phos. Angew. Chem. Int. Ed. 2008 47(10) 2127-2130. [doi]
Shen, Q., Ogata, T., and J. F. Hartwig, Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides and Iodides: Scope and Structure-Activity Relationships. J. Am. Chem. Soc. 2008 130(20) p. 6586-6596. [doi]
Barrios-Landeros, F., Carrow, B.P., and J. F. Hartwig, Autocatalytic Oxidative Addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). J. Am. Chem. Soc. 2008 130(18) p. 5842-5843. [doi]
Hagedorn, K.V., Varnavski, O., Hartwig, J. and T. Goodson III, Exciton Trapping in an Organic Dendrimer Possessing No Energy Gradient. J. Phys. Chem. C. 2008 112(7) p. 2235-2238. [doi]
Hama, T. and J. F. Hartwig, Palladium-Catalyzed a-Arylation of Esters with Chloroarenes. Org. Lett. 2008 10(8) p. 1549-1552. [doi]
Hama, T., and J. F. Hartwig, a-Arylation of Esters Catalyzed by the Pd(I) Dimer {[P(t-Bu)3]PdBr}2. Org. Lett. 2008 10(8) p. 1545-1548. [doi]
Boebel, T. A. and J. F. Hartwig, Silyl-Directed, Iridium-Catalyzed ortho-Borylation of Arenes. A One-Pot ortho-Borylation of Phenols, Arylamines, and Alkylarenes. J. Am. Chem. Soc. 2008 130(24) p. 7534-7535. [doi]
Murphy, J.M., Liao, X., and J. F. Hartwig, Meta Halogenation of 1,3-Disubstituted Arenes via Iridium-Catalyzed Arene Borylation. J. Am. Chem. Soc. 2007 129(50) p. 15434-15435. [doi]
Stambuli, J.P., Weng, Z., Incarvito, C.D., and J. F. Hartwig, Reductive Elimination of Ether from T-Shaped, Monomeric Arylpalladium Alkoxides. Angew. Chem., Int. Ed. 2007 46(40) p. 7674-7677. [doi]
Johns, A.M., Liu, Z., and J. F. Hartwig, Primary tert- and sec-Allylamines via Palladium-Catalyzed Hydroamination and Allylic Substitution with Hydrazine and Hydroxylamine Derivatives. Angew. Chem., Int. Ed. 2007 46(38) p. 7259-7261 [doi]
Markovic, D. and J. F. Hartwig, Resting State and Kinetic Studies on the Asymmetric Allylic Substitutions Catalyzed by Iridium-Phosphoramidite Complexes. J. Am. Chem. Soc., 2007 129(38) p. 11680-11681.
[doi]
Pouy, M. J., Leitner, A., Weix, D. J., Ueno, S. and J. F. Hartwig, Enantioselective Iridium-Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates. Org. Lett., 2007 9(20) p. 3949-3952.
[doi]
Shen, Q. and J. F. Hartwig, Lewis Acid Acceleration of C-N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides. J. Am. Chem. Soc., 2007. 129(25): p. 7734-7735.
[doi]
Weix, D. J. and J. F. Hartwig, Regioselective and Enantioselective Iridium-Catalyzed Allylation of Enamines. J. Am. Chem. Soc., 2007. 129(25): p. 7720-7721.
[doi]
Yamashita, Y., Gopalarathnam, A., and J. F. Hartwig, Iridium-Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids. J. Am. Chem. Soc., 2007. 129(24): p. 7508-7509.
[doi]
Herzon, S. B., and J. F. Hartwig, Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N-Alkyl Arylamines. J. Am. Chem. Soc., 2007. 129(21): p. 6690-6691.
[doi]
Hartwig, J. F. Electronic Effects on Reductive Elimination To Form Carbon-Carbon and Carbon-Heteroatom Bonds from Palladium(II) Complexes. Inorg. Chem, 2007. 46(6): p. 1936-1947.
[doi]
Tzschucke, C. C., Murphy, J. M., and J. F. Hartwig, Arenes to Anilines and Aryl Ethers by Sequential Iridium-Catalyzed Borylation and Copper-Catalyzed Coupling . Org. Lett., 2007. 9(5): p. 761-764.
[doi]
Murphy, J. M., Tzschucke, C. C., and J. F. Hartwig, One-Pot Synthesis of Arylboronic Acids and Aryl Trifluoroborates by Ir-Catalyzed Borylation of Arenes. Org. Lett., 2007. 9(5): p. 757-760.
[doi]
Zhao, P., Incarvito, C. D. and J. F. Hartwig, Directly Observed Transmetalation from Boron to Rhodium. b-Aryl Elimination from Rh(I) Arylboronates and Diarylborinates. J. Am. Chem. Soc, 2007. 129(7): p. 1876-1877.
[doi]
Shekhar, S., and J. F. Hartwig, Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd[P(tBu3)]2. Organometallics, 2007. 26(2): p. 340-351.
[doi]
Johns, A. M, Tye, J. W., and J. F. Hartwig, Relative Rates for the Aminations of h3-Allyl and h3-Benzyl Complexes of Palladium. J. Am. Chem. Soc., 2006. 128(50): p. 16010-16011.
[doi]
Takemiya, A., and J. F. Hartwig, Palladium-Catalyzed Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Anion Equivalent. J. Am. Chem. Soc., 2006. 128(46): p. 14800-14801.
[doi]
Fernandez-Rodríguez, M. A., Shen, Q., and J. F. Hartwig, Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols. Chem.--Eur. J., 2006. 12: p. 7782-7796.
[doi]
Murphy, J. M., Lawrence, J. D., Kawamura, K., Incarvito, C., and J. F. Hartwig, Ruthenium-Catalyzed Regiospecific Borylation of Methyl C-H Bonds. J. Am. Chem. Soc., 2006. vol(iss): p. 13684-13685.
[doi]
Rosenfeld, D. C., Shekhar, S., Takemiya, A., Utsunomiya, M., and J. F. Hartwig, Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal Triflates . Org. Lett., 2006. 8(19): p. 4179-4182.
[doi]
Shekhar, S., Trantow, B., Leitner, A., and J. F. Hartwig, Sequential Catalytic Isomerization and Allylic Substitution. Conversion of Racemic Branched Allylic Carbonates to Enantioenriched Allylic Substitution Products . J. Am. Chem. Soc., 2006. 128(36): p. 11770-11771
[doi]
Su, W.; Raders, S.; Verkade, J.G.; Liao, X; Hartwig, J.F., Palladium-Catalyzed alpha-Arylation of Trimethylsilyl Enol Ethers with Aryl Bromides and Chlorides. A Synergistic Effect of Two Metal Fluorides as Additives. Angew. Chem., 2006. 45(35): p.5852-5855.
[doi]
Shen, Q., and J. F. Hartwig, Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides. J. Am. Chem. Soc., 2006. 128(31): p.10028-10029.
[doi]
Zhao, P., Incarvito, C.D., and J. F. Hartwig, Carbon-Oxygen Bond Formation between a Terminal Alkoxo Ligand and a Coordinated Olefin. Evidence for Olefin Insertion into a Rhodium-Alkoxide. J. Am. Chem. Soc., 2006. 128(30): p.9642-9643.
[doi]
Fujita, K.I., Yamashita, M, Puschmann, F., Alvarez-Falcon, M.M., Incarvito, C.D., and J. F. Hartwig, Organometallic Chemistry from Amidate Complexes. Reductive elimination of N-Aryl Amidates from Palladium(II). J. Am. Chem. Soc., 2006. 128(28): p.9044-9045.
[doi]
J.F. Hartwig, Discovery and Understanding of Transition Metal-Catalyzed Aromatic Substitution Reactions. Synlett, 2006. p.1283-1294.
[doi]
Sakai, N., Ridder, A., J. F. Hartwig, Tropene Derivatives by Sequential Intermolecular and Transannular, Intramolecular Palladium-Catalyzed Hydroamination of Cycloheptatriene. J. Am. Chem. Soc., 2006. 128(25): p.8134-8135.
[doi]
Johns, A.M., Sakai, N., Ridder, A., and J. F. Hartwig, Direct Measurement of the Thermodynamics of Vinylarene Hydroamination. J. Am. Chem. Soc., 2006. 128(29): p.9306-9307.
[doi]
Takemiya, A., and J.F. Hartwig, Rhodium-Catalyzed Intramolecular, Anti-Markovnikov Hydroamination. Synthesis of 3-Arylpiperidines. J. Am. Chem. Soc., 2006. 128(18):15 p.6042-6043.
[doi]
Hama, T., Culkin, D. A., and J. F. Hartwig, Palladium-Catalyzed Intermolecular a-Arylation of Zinc Amide Enolates under Mild Conditions. J. Am. Chem. Soc., 2006. 128(15): p. 4976-4985.
[doi]
Johns, A. M., Utsunomiya, M., Incarvito, C. D., and J. F. Hartwig, A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes. J. Am. Chem. Soc., 2006. 128(6): p. 1828-1839.
[doi]
Fernández-Rodríguez, M. A., Shen, Q., and J. F. Hartwig, A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols. J. Am. Chem. Soc., 2006. 128(7): p. 2180-2181.
[doi]
Shekhar, S., Ryberg, P., and J. F. Hartwig, Oxidative Addition of Phenyl Bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for Addition to Pd(BINAP). Org. Lett., 2006. 8(5): p. 851-854.
[doi]
Shekhar, S., Ryberg, P., Hartwig, J. F., Mathew, J. S., Blackmond, D. G., Strieter, E. R., and S. L. Buchwald, Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes. J. Am. Chem. Soc., 2006. 128(11): p. 3584-3591.
[doi]
Zhao, P., Incarvito, C. D., and J. F. Hartwig, Direct Observation of b-Aryl Eliminations from Rh(I) Alkoxides. J. Am. Chem. Soc., 2006. 128(10): p. 3124-3125.
[doi]
Barrios-Landeros, F. and J. F. Hartwig, Distinct Mechanisms for the Oxidative Addition of Chloro-, Bromo-, and Iodoarenes to a Bisphosphine Palladium(0) Complex with Hindered Ligands. J. Am. Chem. Soc., 2005. 127(19): p. 6944-6945.
[doi]
Bae, C., Hartwig, J. F., Boaen Harris, N. K., Long, R. O., Anderson, K. S., and M. A. Hillmyer, Catalytic Hydroxylation of Polypropylenes. J. Am. Chem. Soc., 2005. 127(2): p. 767-776.
[doi]
Boller, T. M., Murphy, J. M., Hapke, M., Ishiyama, T., Miyaura, N., and J. F. Hartwig, Mechanism of the Mild Functionalization of Arenes by Diboron Reagents Catalyzed by Iridium Complexes. Intermediacy and Chemistry of Bipyridine-Ligated Iridium Trisboryl Complexes. J. Am. Chem. Soc., 2005. 127(41): p. 14263-14278.
[doi]
Graening, T. and J. F. Hartwig, Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates. J. Am. Chem. Soc., 2005. 127(49): p. 17192-17193.
[doi]
Hartwig, J. F., Synthetic Chemistry: Recipes for Excess. Nature, 2005. 437: p. 487-488
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Hartwig, J. F., Cook, K. S., Hapke, M., Incarvito, C. D., Fan, Y., Webster, C. E., and M. B. Hall, Rhodium Boryl Complexes in the Catalytic, Terminal Functionalization of Alkanes. J. Am. Chem. Soc., 2005. 127(8): p. 2538-2552.
[doi]
Lee, D.-Y. and J. F. Hartwig, Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates. Org. Lett., 2005. 7(6): p. 1169-1172.
[doi]
Leitner, A., Shekhar, S., Pouy, M. J., and J. F. Hartwig, A Simple Iridium Catalyst with a Single Resolved Stereocenter for Enantioselective Allylic Amination. Catalyst Selection from Mechanistic Analysis. J. Am. Chem. Soc., 2005. 127(44): p. 15506-15514.
[doi]
Leitner, A., Shu, C., and J. F. Hartwig, Effects of Catalyst Activation and Ligand Steric Properties on the Enantioselective Allylation of Amines and Phenoxides. Org. Lett., 2005. 7(6): 1093-1096.
[doi]
Limmert, M. E., Roy, A. H., and J. F. Hartwig, Kumada Coupling of Aryl and Vinyl Tosylates under Mild Conditions. J. Org. Chem., 2005. 127(45): p. 9364-9370.
[doi]
Shen, Q., Shekhar, S., Stambuli, J. P., and J. F. Hartwig, Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles. Angewandte Chemie International Edition, 2005. 44(9): p. 1371-1375.
[abstract]
Takaya, J. and J. F. Hartwig, Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through p-Arene Complexes. J. Am. Chem. Soc., 2005. 127(16): p. 5756-5757.
[doi]
Tsukada, N. and J. F. Hartwig, Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C-H Bonds. J. Am. Chem. Soc., 2005. 127(14): p. 5022-5023.
[doi]
Wu, L. and J. F. Hartwig, Mild Palladium-Catalyzed Selective Monoarylation of Nitriles. J. Am. Chem. Soc., 2005. 127(45): p. 15824-15832.
[doi]
Yan, X. Z., Pawlas, J., Goodson, T., III and J. F. Hartwig, Polaron Delocalization in Ladder Macromolecular Systems. J. Am. Chem. Soc., 2005. 127(25): p. 9105-9116.
[doi]
Zhao, J., Goldman, A. S., and J. F. Hartwig, Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex. Science, 2005. 307(5712): p. 1080-1082.
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Zhao, J. and J. F. Hartwig, Acceptorless, Neat, Ruthenium-Catalyzed Dehydrogenative Cyclization of Diols to Lactones. Organometallics, 2005. 24(10): p. 2441-2446.
[doi]
Zhao, P., Krug, C., and J. F. Hartwig, Transfer of Amido Groups from Isolated Rhodium(I) Amides to Alkenes and Vinylarenes. J. Am. Chem. Soc., 2005. 127(34): p. 12066-12073.
[doi]
Zhao, P. and J. F. Hartwig, b-Aryl Eliminations from Rh(I) Iminyl Complexes. J. Am. Chem. Soc., 2005. 127(33): p. 11618-11619.
[doi]
Cook, K. S., Incarvito, C. D., Webster, C. E., Fan, Y., Hall, M. B. and J. F. Hartwig, Rhodium Silyl Boryl Hydride Complexes: Comparison of Bonding and the Rates of Elimination of Borane, Silane, and Dihydrogen. Angewandte Chemie International Edition, 2004. 43(41): p. 5474-5477.
[abstract]
Culkin, D. A. and J. F. Hartwig, Carbon-Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity. Organometallics, 2004. 23(14): p. 3398-3416.
[doi]
Krug, C. and J. F. Hartwig, Imine Insertion into a Late Metal-Carbon Bond To Form a Stable Amido Complex. J. Am. Chem. Soc., 2004. 126(9): p. 2694-2695.
[doi]
Krug, C. and J. F. Hartwig, Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions. Organometallics, 2004. 23(20): p. 4594-4607.
[doi]
Lawrence, J. D., Takahashi, M., Bae, C. and J. F. Hartwig, Regiospecific Functionalization of Methyl C-H Bonds of Alkyl Groups in Reagents with Heteroatom Functionality. J. Am. Chem. Soc., 2004. 126(47): p. 15334-15335.
[doi]
Leitner, A., Larsen, J., Steffens, C. and J. F. Hartwig, Palladium-Catalyzed Addition of Mono- and Dicarbonyl Compounds to Conjugated Dienes. J. Org. Chem., 2004. 69(22): p. 7552-7557.
[doi]
Leitner, A., Shu, C., and J. F. Hartwig, Editing the Stereochemical Elements in an Iridium Catalyst for Enantioselective Allylic Amination. Proc. Nat. Acad. Sci. U.S.A., 2004. 101(16): p. 5830-5833.
[abstract]
Liu, X. and J. F. Hartwig, Palladium-Catalyzed a-Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of a-Aryl Carboxylic Acid Derivatives. J. Am. Chem. Soc., 2004. 126(16): p. 5182-5191.
[doi]
Roy, A. H. and J. F. Hartwig, Oxidative Addition of Aryl Sulfonates to Palladium(0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism. Organometallics, 2004. 23(2): p. 194-202.
[doi]
Roy, A. H. and J. F. Hartwig, Reductive Elimination of Aryl Halides upon Addition of Hindered Alkylphosphines to Dimeric Arylpalladium(II) Halide Complexes. Organometallics, 2004. 23(7): p. 1533-1541.
[doi]
Shekhar, S. and J. F. Hartwig, Distinct Electronic Effects on Reductive Eliminations of Symmetrical and Unsymmetrical Bis-Aryl Platinum Complexes. J. Am. Chem. Soc., 2004. 126(40): p 13016-13027.
[doi]
Shu, C., Leitner, A. and J. F. Hartwig, Enantioselective Allylation of Aromatic Amines after In Situ Generation of an Activated Cyclometalated Iridium Catalyst. Angewandte Chemie International Edition, 2004. 43(36): p. 4797-4800.
[abstract]
Shu, C. and J. F. Hartwig, Iridium-Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. Angewandte Chemie International Edition, 2004. 43(36): p. 4794-4797.
[abstract]
Stambuli, J. P., Incarvito, C. D., Buhl, M. and J. F. Hartwig, Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction. J. Am. Chem. Soc., 2004. 126(4): p 1184-1194.
[doi]
Utsunomiya, M. and J. F. Hartwig, Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. J. Am. Chem. Soc., 2005. 126(9): p 2702-2703.
[doi]
Yamashita, M. and J. F. Hartwig, Synthesis, Structure, and Reductive Elimination Chemistry of Three-Coordinate Arylpalladium Amido Complexes. J. Am. Chem. Soc., 2004. 126(17): p 5344-5345.
[doi]
Anastasi, N. R., Waltz, K. M., Weerakoon, W. L., and J. F. Hartwig, A short synthesis of tetraalkoxydiborane(4) reagents. Organometallics, 2003. 22(2): p. 365-369.
[doi]
Culkin, D. A. and J. F. Hartwig, Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Accounts of Chemical Research, 2003. 36(4): p. 234-245.
[doi]
Hama, T., Liu, X., Culkin, D. A., and J. F. Hartwig, Palladium-Catalyzed a-Arylation of Esters and Amides under More Neutral Conditions. J. Am. Chem. Soc., 2003. 125(37): p. 11176-11177.
[doi]
Hooper, M. W., Utsunomiya, M., and J. F. Hartwig, Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. J. Org. Chem., 2003. 68(7): p. 2861-2873.
[doi]
Hooper, M. W. and J. F. Hartwig, Understanding the Coupling of Heteroaromatic Substrates: Synthesis, Structures, and Reductive Eliminations of Heteroarylpalladium Amido Complexes. Organometallics, 2003. 22(17): p. 3394-3403.
[doi]
Ishiyama, T., Takagi, J., Yonekawa, Y., Hartwig, J. F., and N. Miyaura, Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions. Advanced Synthesis and Catalysis, 2003. 345(9-10): p. 1103-1106.
[link]
Ishiyama, T., Nobuta, Y., Hartwig, J. F., and N. Miyaura, Room Temperature Borylation of Arenes and Heteroarenes Using Stoichiometric Amounts of Pinacolborane Catalyzed by Iridium Complexes in an Inert Solvent. Chemical Communications, 2003. 23: p. 2924-2925.
[link]
Kanzelberger, M., Zhang, X., Emge, T. J., Goldman, A. S., Zhao, J., Incarvito, C. D., and J. F. Hartwig, Distinct Thermodynamics for the Formation and Cleavage of N-H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex. J. Am. Chem. Soc., 2003. 125(45): p. 13644-13645.
[doi]
Kiener, C. A., Shu, C., Incarvito, C. D., and J. F. Hartwig, Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity. J. Am. Chem. Soc., 2003. 125(47): p. 14272 -14273.
[doi]
Liu, X. and J. F. Hartwig, Palladium-catalyzed a-arylation of azlactones to form quaternary amino acid derivatives. Organic Letters, 2003. 5(11): p. 1915-1918.
[doi]
Lopez, F., Ohmura, T., and J. F. Hartwig, Regio- and Enantioselective Iridium-Catalyzed Intermolecular Allylic Etherification of Achiral Allylic Carbonates with Phenoxides. J. Am. Chem. Soc., 2003. 125(12): p. 3426-3427.
[doi]
Mann, G., Shelby, Q., Roy, A. H., and J. F. Hartwig, Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II). Organometallics, 2003. 22(13): p. 2775-2789.
[doi]
Roy, A. H. and J. F. Hartwig, Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes. J. Am. Chem. Soc., 2003. 125(46): p. 13944-13945.
[doi]
Roy, A. H. and J. F. Hartwig, Oxidative Addition of Aryl Tosylates to Palladium(0) and Coupling of Unactivated Aryl Tosylates at Room Temperature. J. Am. Chem. Soc., 2003. 125(29): p. 8704-8705.
[doi]
Stambuli, J. P. and J. F. Hartwig, Recent Advances in the Discovery of Organometallic Catalysts Using High-Throughput Screening Assays. Current Opinion in Chemical Biology, 2003. 7(3): p 420-426.
[doi]
Stauffer, S. R. and J. F. Hartwig, Fluorescence Resonance Energy Transfer (FRET) as a High-Throughput Assay for Coupling Reactions. Arylation of Amines as a Case Study. J. Am. Chem. Soc., 2003. 125(23): p. 6977-6985.
[doi]
Utsunomiya, M., Kawatsura, M., and J. F. Hartwig, Palladium-Catalyzed Equilibrium Addition of Acidic OH Groups across Dienes. Angewandte Chemie International Edition, 2003. 42(47): p. 5865-5868.
[link]
Utsunomiya, M., Kuwano, R., Kawatsura, M., and J. F. Hartwig, Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. J. Am. Chem. Soc., 2003. 125(19): p. 5608-5609.
[doi]
Utsunomiya, M. and J. F. Hartwig, Intermolecular, Markovnikov Hydroamination of Vinylarenes with Alkylamines. J. Am. Chem. Soc., 2003. 125(47): p. 14286-14287.
[doi]
Webster, C. E., Fan, Y., Hall, M. B., Kunz, D., and J. F. Hartwig, Experimental and Computational Evidence for a Boron-Assisted, Sigma-Bond Metathesis Pathway for Alkane Borylation. J. Am. Chem. Soc., 2003. 125(4): p. 858-859.
[doi]
Yamashita, M., Cuevas Vicario, J. V., and J. F. Hartwig, Trans Influence on the Rate of Reductive Elimination. Reductive Elimination of Amines from Isomeric Arylpalladium Amides with Unsymmetrical Coordination Spheres. J. Am. Chem. Soc., 2003. 125(52): p. 16347-16360.
[doi]
Alcazar-Roman, L. M. and J. F. Hartwig, Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine. Organometallics, 2002. 21(3): p. 491-502.
[doi]
Beare, N. A. and J. F. Hartwig, Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. J. Org. Chem., 2002. 67(2): p. 541-555.
[doi]
Culkin, D. A. and J. F. Hartwig, Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: Selection of catalysts for the alpha-arylation of nitriles. J. Am. Chem. Soc., 2002. 124(32): p. 9330-9331.
[doi]
Hartwig, J. F., Raising the bar for the "Perfect reaction". Science, 2002. 297(5587): p. 1653-1654.
[abstract][pdf]
Ishiyama, T., Takagi, J., Hartwig, J. F., and N. Miyaura, A stoichiometric aromatic C-H borylation catalyzed by iridium(I)/2,2 '-bipyridine complexes at room temperature. Angewandte Chemie-International Edition, 2002. 41(16): p. 3056-3058.
[abstract][pdf]
Ishiyama, T., Takagi, J., Ishida, K., Miyaura, N., Anasrasi, N. R., and J. F. Hartwig, Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. J. Am. Chem. Soc., 2002. 124(3): p. 390-391.
[doi]
Jorgensen, M., Lee, S., Liu, X., Wolkowski, J. P., and J. F. Hartwig, Efficient synthesis of a-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. J. Am. Chem. Soc., 2002. 124(42): p. 12557-12565.
[doi]
Kataoka, N., Shelby, Q., Stambuli, J. P., and J. F. Hartwig, Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C-C, C-N, and C-O bond-forming cross-couplings. J. Org. Chem., 2002. 67(16): p. 5553-5566.
[doi]
Kondo, Y., Garcia-Cuadrado, D., Hartwig, J. F., Boaen, N. K., Wagner, N. L. and A. M. Hillmyer, Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. J. Am. Chem. Soc., 2002. 124(7): p. 1164-1165.
[doi]
Krug, C. and J. F. Hartwig, Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J. Am. Chem. Soc., 2002. 124(8): p. 1674-1679.
[doi]
Kuwano, R., Utsunomiya, M., and J. F. Hartwig, Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. J. Org. Chem., 2002. 67(18): p. 6479-6486.
[doi]
Nettekoven, U. and J. F. Hartwig, A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J. Am. Chem. Soc., 2002. 124(7): p. 1166-1167.
[doi]
Ohmura, T. and J. F. Hartwig, Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J. Am. Chem. Soc., 2002. 124(51): p. 15164-15165.
[doi]
Pawlas, J., Nakao, Y., Kawatsura, M., J. F. Hartwig, A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: Catalyst selection, scope, and mechanism. J. Am. Chem. Soc., 2002. 124(14): p. 3669-3679.
[doi]
Ranasinghe, M. I., Varnavski, O. P., Pawlas, J., Hauck, S. I., Louie, J., Hartwig, J. F., and T. Goodson III, Femtosecond excitation energy transport in triarylamine dendrimers. J. Am. Chem. Soc., 2002. 124(23): p. 6520-6521.
[doi]
Schlummer, B. and J. F. Hartwig, Bronsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Organic Letters, 2002. 4(9): p. 1471-1474.
[doi]
Stambuli, J. P., Kuwano, R., and J. F. Hartwig, Unparalleled rates for the activation of aryl chlorides and bromides: Coupling with amines and boronic acids in minutes at room temperature. Angewandte Chemie-International Edition, 2002. 41(24): p. 4746-4748.
[abstract][pdf]
Stambuli, J. P., Buhl, M., and J. F. Hartwig, Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc., 2002. 124(32): p. 9346-9347.
[doi]
Takagi, J., Sato, K., Hartwig, J. F., Ishiyama, T., and N. Miyaura, Iridium-catalyzed C-H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates. Tetrahedron Letters, 2002. 43(32): p. 5649-5651.
[abstract][pdf]
Wolkowski, J. P. and J. F. Hartwig, Generation of Reactivity from Typically Stable Ligands: C-C Bond-Forming Reductive Elimination from Aryl Palladium(II) Complexes of Malonate Anions. Angewandte Chemie-International Edition, 2002. 114(22): p. 4465-4467.
[abstract][pdf]
Alcazar-Roman, L. M. and J. F. Hartwig, Mechanism of aryl chloride amination: Base-induced oxidative addition. J. Am. Chem. Soc., 2001. 123(51): p. 12905-12906.
[doi]
Chae, H. K., Eddaoudi, M., Kim, J., Hauck, S. I., Hartwig, J. F., O'Keeffe, M., and O. M. Yaghi, Tertiary building units: Synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1). J. Am. Chem. Soc., 2001. 123(46): p. 11482-11483.
[doi]
Culkin, D. A. and J. F. Hartwig, C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. J. Am. Chem. Soc., 2001. 123(24): p. 5816-5817.
[doi]
Hartwig, J. F., Taking it personally. Chemical & Engineering News, 2001. 79(13): p. 248-248.
Kawamura, K. and J. F. Hartwig, Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. J. Am. Chem. Soc., 2001. 123(34): p. 8422-8423.
[doi]
Kawatsura, M. and J. F. Hartwig, Transition metal-catalyzed addition of amines to acrylic acid derivatives. A high-throughput method for evaluating hydroamination of primary and secondary alkylamines. Organometallics, 2001. 20(10): p. 1960-1964.
[doi]
Lee, S., Beare, N. A., and J. F. Hartwig, Palladium-catalyzed alpha-arylation of esters and protected amino acids. J. Am. Chem. Soc., 2001. 123(34): p. 8410-8411.
[doi]
Lee, S., M. Jorgensen, and J. F. Hartwig, Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. Organic Letters, 2001. 3(17): p. 2729-2732.
[doi]
Lee, S. and J. F. Hartwig, Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide a-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. J. Org. Chem., 2001. 66(10): p. 3402-3415.
[doi]
Lober, O., Kawatsura, M., and J. F. Hartwig, Palladium-catalyzed hydroamination of 1,3-dienes: A colorimetric assay and enantioselective additions. J. Am. Chem. Soc., 2001. 123(18): p. 4366-4367.
[doi]
Roy, A. H. and J. F. Hartwig, Reductive elimination of aryl halides from palladium(II). J. Am. Chem. Soc., 2001. 123(6): p. 1232-1233.
[doi]
Stambuli, J. P., Stauffer, S. R., Shaughnessy, K. H., and J. F. Hartwig, Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. J. Am. Chem. Soc., 2001. 123(11): p. 2677-2678.
[doi]
Stauffer, S. R., Beare, N .A., Stambuli, J. P., and J. F. Hartwig, Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. J. Am. Chem. Soc., 2001. 123(19): p. 4641-4642.
[doi]
Zhao, J., Hesslink, H., and J. F. Hartwig, Mechanism of b-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. J. Am. Chem. Soc., 2001. 123(30): p. 7220-7227.
[doi]
Alcazar-Roman, L. M., Hartwig, J. F., Rheingold, A. L., Liable-Sands, L. M., and I. A. Guzei, Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition. J. Am. Chem. Soc., 2000. 122(19): p. 4618-4630.
[doi]
Chen, H. Y., Schlecht, S., Semple, T. C., and J. F. Hartwig, Thermal, catalytic, regiospecific functionalization of alkanes. Science, 2000. 287(5460): p. 1995-1997.
[abstract][pdf]
Hartwig, J. F. and C. N. Muhoro, Mechanistic studies of titanocene-catalyzed alkene and alkyne hydroboration: Borane complexes as catalytic intermediates. Organometallics, 2000. 19(1): p. 30-38.
[doi]
Ishiyama, T. and J. Hartwig, A Heck-type reaction involving carbon-heteroatom double bonds. Rhodium(I)-catalyzed coupling of aryl halides with N-pyrazyl aldimines. J. Am. Chem. Soc., 2000. 122(48): p. 12043-12044.
[doi]
Kawatsura, M. and J. F. Hartwig, Palladium-catalyzed intermolecular hydroamination of vinylarenes using arylamines. J. Am. Chem. Soc., 2000. 122(39): p. 9546-9547.
[doi]
Schlecht, S. and J. F. Hartwig, s-borane complexes of manganese and rhenium. J. Am. Chem. Soc., 2000. 122(39): p. 9435-9443.
[doi]
Stauffer, S. R., Lee, S., Stambuli, J. P., Hauck, S. I., and J. F. Hartwig, High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. Organic Letters, 2000. 2(10): p. 1423-1426.
[doi]
Waltz, K. M. and J. F. Hartwig, Functionalization of alkanes by isolated transition metal boryl complexes. J. Am. Chem. Soc., 2000. 122(46): p. 11358-11369.
[doi]
Chen, H. Y. and J. F. Hartwig, Catalytic, regiospecific end-functionalization of alkanes: Rhenium-catalyzed borylation under photochemical conditions. Angewandte Chemie-International Edition, 1999. 38(22): p. 3391-3393.
[abstract][pdf]
Goodson, F. E., Hauck, S. I., and J. F. Hartwig, Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines. J. Am. Chem. Soc., 1999. 121(33): p. 7527-7539.
[doi]
Hartwig, J. F., Approaches to catalyst discovery. New carbon-heteroatom and carbon-carbon bond formation. Pure and Applied Chemistry, 1999. 71(8): p. 1417-1423.
Hartwig, J. F., Kawatsura, M., Hauck, S. I., Shaughnessy, K. H., and L. M. Alcazar-Roman Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand. J. Org. Chem., 1999. 64(15): p. 5575-5580.
[doi]
Hauck, S. I., Lakshmi, K. V. and J. F. Hartwig, Tetraazacyclophanes by palladium-catalyzed aromatic amination. Geometrically defined, stable, high-spin diradicals. Organic Letters, 1999. 1(13): p. 2057-2060.
[doi]
Kawatsura, M. and J. F. Hartwig, Simple, highly active palladium catalysts for ketone and malonate arylation: Dissecting the importance of chelation and steric hindrance. J. Am. Chem. Soc., 1999. 121(7): p. 1473-1478.
[doi]
Mann, G., Incarvito, C. D., Rheingold, A. L., and J. F. Hartwig, Palladium-catalyzed C-O coupling involving unactivated aryl halides. Sterically induced reductive elimination to form the C-O bond in diaryl ethers. J. Am. Chem. Soc., 1999. 121(13): p. 3224-3225.
[doi]
Muhoro, C. N., He, X. M., and J. F. Hartwig, Titanocene borane sigma-complexes. J. Am. Chem. Soc., 1999. 121(21): p. 5033-5046.
[doi]
Shaughnessy, K. H., Kim, P., and J. F. Hartwig, A fluorescence-based assay for high-throughput screening of coupling reactions. Application to Heck chemistry. J. Am. Chem. Soc., 1999. 121(10): p. 2123-2132.
[doi]
Waltz, K. M., Muhoro, C. N., and J. F. Hartwig, C-H activation and functionalization of unsaturated hydrocarbons by transition-metal boryl complexes. Organometallics, 1999. 18(17): p. 3383-3393.
[doi]
Driver, M. S. and J. F. Hartwig, Oxidative addition and reductive elimination reactions of trans-[Ir(PPh3)2(CO)(NC4H4)] and trans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)] including N-H bond-forming reductive elimination of pyrrole. Organometallics, 1998. 17(6): p. 1134-1143.
[doi]
Goodson, F. E. and J. F. Hartwig, Regiodefined poly(N-arylaniline)s and donor-acceptor copolymers via palladium-mediated amination chemistry. Macromolecules, 1998. 31(5): p. 1700-1703.
[doi]
Hamann, B. C. and J. F. Hartwig, Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates. J. Am. Chem. Soc., 1998. 120(48): p. 12706-12706.
[doi]
Hamann, B. C. and J. F. Hartwig, Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates. J. Am. Chem. Soc., 1998. 120(29): p. 7369-7370.
[doi]
Hamann, B. C. and J. F. Hartwig, Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations. J. Am. Chem. Soc., 1998. 120(15): p. 3694-3703.
[doi]
Hartwig, J. F., Carbon-heteroatom bond-forming reductive eliminations of amines, ethers, and sulfides. Accounts of Chemical Research, 1998. 31(12): p. 852-860.
[doi]
Hartwig, J. F., Transition metal catalyzed synthesis of arylamines and aryl ethers from aryl halides and triflates: Scope and mechanism. Angewandte Chemie-International Edition, 1998. 37(15): p. 2047-2067.
[abstract][pdf]
Hartwig, J. F., Synthesis, structure, and reactivity of a palladium hydrazonato complex: A new type of reductive elimination reaction to form C-N bonds and catalytic arylation of benzophenone hydrazone. Angewandte Chemie-International Edition, 1998. 37(15): p. 2090-2093.
[abstract][pdf]
Louie, J. and J. F. Hartwig, The largest discrete oligo(m-aniline). An exponential growth strategy using palladium-catalyzed amination of aryl sulfonates. Macromolecules, 1998. 31(19): p. 6737-6739.
[doi]
Mann, G., Baranano, D., Hartwig, J. F., Rheingold, A. L., and I. A. Guzei, Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation. J. Am. Chem. Soc., 1998. 120(36): p. 9205-9219.
[doi]
Mann, G., Hartwig, J. F., Driver, M. S., and C. Fernandez-Rivas, Palladium-catalyzed C-N(sp2) bond formation: N-arylation of aromatic and unsaturated nitrogen and the reductive elimination chemistry of palladium azolyl and methyleneamido complexes. J. Am. Chem. Soc., 1998. 120(4): p. 827-828.
[doi]
Shaughnessy, K. H., Hamann, B. C., and J. F. Hartwig, Palladium-catalyzed inter- and intramolecular alpha-arylation of amides. Application of intramolecular amide arylation to the synthesis of oxindoles. J. Org. Chem., 1998. 63(19): p. 6546-6553.
[doi]
Baranano, D., Mann, G., and J. F. Hartwig, Nickel and palladium-catalyzed cross-couplings that form carbon-heteroatom and carbon-element bonds. Current Organic Chemistry, 1997. 1(3): p. 287-305.
Driver, M. S. and J. F. Hartwig, Energetics and mechanism of alkylamine N-H bond cleavage by palladium hydroxides: N-H activation by unusual acid-base chemistry. Organometallics, 1997. 16(26): p. 5706-5715.
[doi]
Driver, M. S. and J. F. Hartwig, Carbon-nitrogen-bond-forming reductive elimination of arylamines from palladium(II) phosphine complexes. J. Am. Chem. Soc., 1997. 119(35): p. 8232-8245.
[doi]
Hamann, B. C. and J. F. Hartwig, Palladium-catalyzed direct alpha-arylation of ketones. Rate acceleration by sterically hindered chelating ligands and reductive elimination from a transition metal enolate complex. J. Am. Chem. Soc., 1997. 119(50): p. 12382-12383.
[doi]
Hartwig, J. F., Palladium-catalyzed amination of aryl halides: Mechanism and rational catalyst design. Synlett, 1997. (4): p. 329-340.
[pdf]
Louie, J., Hartwig, J. F., and A. J. Fry, Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination. J. Am. Chem. Soc., 1997. 119(48): p. 11695-11696.
[doi]
Louie, J., Driver, M. S., Hamann, B. C., and J. F. Hartwig, Palladium-catalyzed amination of aryl triflates and importance of triflate addition rate. J. Org. Chem., 1997. 62(5): p. 1268-1273.
[doi]
Mann, G. and J. F. Hartwig, Palladium-catalyzed formation of diaryl ethers from aryl bromides. Electron poor phosphines enhance reaction yields. Tetrahedron Letters, 1997. 38(46): p. 8005-8008.
[abstract][pdf]
Mann, G. and J. F. Hartwig, Nickel- vs palladium-catalyzed synthesis of protected phenols from aryl halides. J. Org. Chem., 1997. 62(16): p. 5413-5418.
[doi]
Muhoro, C. N. and J. F. Hartwig, Synthesis, structure, and reactivity of [Cp2Ti(HBcat)(PMe3)]: A monoborane sigma complex. Angewandte Chemie-International Edition, 1997. 36(13-14): p. 1510-1512.
Waltz, K. M. and J. F. Hartwig, Selective functionalization of alkanes by transition-metal boryl complexes. Science, 1997. 277(5323): p. 211-213.
[pdf]
Driver, M. S. and J. F. Hartwig, A second-generation catalyst for aryl halide amination: Mixed secondary amines from aryl halides and primary amines catalyzed by (DPPF)PdCl2. J. Am. Chem. Soc., 1996. 118(30): p. 7217-7218.
[doi]
Driver, M. S. and J. F. Hartwig, General N-H activation of primary alkylamines by a late transition-metal complex. J. Am. Chem. Soc., 1996. 118(17): p. 4206-4207.
[doi]
Hartwig, J. F. and X. M. He, Structural and reaction chemistry of tungstenocene boryl complexes. Organometallics, 1996. 15(25): p. 5350-5358.
[doi]
Hartwig, J. F., Muhoro, C. N., He, X., Eisenstein, O., Bosque, R., and F. Maseras, Catecholborane bound to titanocene. Unusual coordination of ligand sigma-bonds. J. Am. Chem. Soc., 1996. 118(44): p. 10936-10937.
[doi]
Hartwig, J. F., Directly-observed b-hydrogen elimination of a late transition metal amido complex and unusual fate of imine byproducts. J. Am. Chem. Soc., 1996. 118(29): p. 7010-7011.
[doi]
Hartwig, J. F., Richards, S., Baranano, D., and F. Paul, Influences on the relative rates for C-N bond-forming reductive elimination and beta-hydrogen elimination of amides. A case study on the origins of competing reduction in the palladium-catalyzed amination of aryl halides. J. Am. Chem. Soc., 1996. 118(15): p. 3626-3633.
[doi]
Hartwig, J. F. and X. M. He, Reactivity of tungstenocene with B-B and B-H bonds versus C-H bonds. Angewandte Chemie-International Edition in English, 1996. 35(3): p. 315-317.
He, X. M. and J. F. Hartwig, True metal-catalyzed hydroboration with titanium. J. Am. Chem. Soc., 1996. 118(7): p. 1696-1702.
[doi]
He, X. M. and J. F. Hartwig, Boryls bound to iron carbonyl. Structure of a rare bis(boryl) complex, synthesis of the first anionic boryl, and reaction chemistry that includes the synthetic equivalent of boryl anion transfer. Organometallics, 1996. 15(1): p. 400-407.
[doi]
Louie, J. and J. F. Hartwig, A route to Pd-0 from Pd-II metallacycles in amination and cross-coupling chemistry. Angewandte Chemie-International Edition in English, 1996. 35(20): p. 2359-2361.
Louie, J., F. Paul, and J. F. Hartwig, Catalysis with platinum-group alkylamido complexes, the active palladium amide in catalytic aryl halide aminations as deduced from kinetic data and independent generation. Organometallics, 1996. 15(12): p. 2794-2805.
[doi]
Mann, G. and J. F. Hartwig, Palladium alkoxides: Potential intermediacy in catalytic amination, reductive elimination of ethers, and catalytic etheration. Comments on alcohol elimination from Ir(III). J. Am. Chem. Soc., 1996. 118(51): p. 13109-13110.
[doi]
Rablen, P. R. and J. F. Hartwig, Accurate borane sequential bond dissociation energies by high-level ab initio computational methods. J. Am. Chem. Soc., 1996. 118(19): p. 4648-4653.
[doi]
Baranano, D. and J. F. Hartwig, Carbon-Heteroatom Bond-Forming Reductive Elimination - Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects During Formation of Aryl Sulfides. J. Am. Chem. Soc., 1995. 117(10): p. 2937-2938.
[first page][pdf]
Driver, M. S. and J. F. Hartwig, A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by 3-Coordinate Intermediates. J. Am. Chem. Soc., 1995. 117(16): p. 4708-4709.
[first page][pdf]
Paul, F., Patt, J., and J. F. Hartwig, Structural Characterization and Simple Synthesis of (Pd[P(O-Tol)3]2), Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides, and Corresponding Monometallic Amine Complexes. Organometallics, 1995. 14(6): p. 3030-3039.
[first page][pdf]
Hartwig, J. F. and F. Paul, Oxidative Addition of Aryl Bromide after Dissociation of Phosphine from a 2-Coordinate Palladium(0) Complex, Bis(Tri-O-Tolylphosphine)Palladium(0). J. Am. Chem. Soc., 1995. 117(19): p. 5373-5374.
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Louie, J. and J. F. Hartwig, Transmetalation Involving Organotin Aryl, Thiolate, and Amide Compounds - an Unusual Type of Dissociative Ligand Substitution-Reaction. J. Am. Chem. Soc., 1995. 117(46): p. 11598-11599.
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Louie, J. and J. F. Hartwig, Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides - Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents. Tetrahedron Letters, 1995. 36(21): p. 3609-3612.
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Waltz, K.M., He, X., Muhoro, C., and J. F. Hartwig, Hydrocarbon Functionalization by Transition-Metal Boryls. J. Am. Chem. Soc., 1995. 117(45): p. 11357-11358.
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Hartwig, J. F. and S. R. De Gala, A Continuum Resulting from Equilibrium between 2 Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes - p-Bonding in a d2 Boryl System and the First d0 Boryl Complex. J. Am. Chem. Soc., 1994. 116(8): p. 3661-3662.
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Hartwig, J. F., Bhandari, S., and P. R. Rablen, Addition of Catecholborane to a Ruthenium-Alkyl - Evidence for Sigma-Bond Metathesis with a Low-Valent, Late Transition-Metal. J. Am. Chem. Soc., 1994. 116(5): p. 1839-1844.
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Paul, F., Patt, J., and J. F. Hartwig, Palladium-Catalyzed Formation of Carbon-Nitrogen Bonds - Reaction Intermediates and Catalyst Improvements in the Hetero Cross-Coupling of Aryl Halides and Tin Amides. J. Am. Chem. Soc., 1994. 116(13): p. 5969-5970.
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Rablen, P. R., Hartwig, J. F., and S. P. Nolan, First Transition Metal-Boryl Bond-Energy and Quantitation of Large Differences in Sequential Bond-Dissociation Energies of Boranes. J. Am. Chem. Soc., 1994. 116(9): p. 4121-4122.
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Hartwig, J. F. and S. Huber, Transition-Metal Boryl Complexes - Structure and Reactivity of CpFe(CO)2Bcat and CpFe(CO)2BPh2. J. Am. Chem. Soc., 1993. 115(11): p. 4908-4909.
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