Journal Articles (2008 - 2009)
2009
"Oxidative Addition of Thioesters to Fe(0): Active-Site Models For Hmd, Nature’s Third Hydrogenase" A. M. Royer, T. B. Rauchfuss, and D. L. Gray Organometallics, 2009, (accepted for publication).
"Nickel-Iron-Dithiolato-Hydrides Relevant to the [NiFe]-Hydrogenase Active Site" B. E. Barton, C. M. Whaley, T. B. Rauchfuss, D. L. Gray, J. Am Chem. Soc., 2009 131, (in press).
"Proton-Assisted Activation of Dihydrogen: Mechanistic Aspects of Proton-Catalyzed Addition of H2 to Ru and Ir Amido Complexes," Z. M. Heiden, T. B. Rauchfuss, J. Am Chem. Soc. 2009, 131, 3593-3600.
"π-Complexes of Lignols with Mn(I) and Ru(II)," D. Morvan, T. B. Rauchfuss, S. R. Wilson, Organometallics 2009, 28, (in press).
"Coordination Chemistry of [HFe(CN)2(CO)3]- and Its Derivatives: Toward a Model for the Iron Subsite of the [NiFe]-Hydrogenases," C. M. Whaley, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem. 2009, 49, 4462-4469.
"Redox-Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands", J. L. Boyer, T. Cundari, N. J. DeYonker, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem., 2009, 49, 638-645.
"Small Molecule Mimics of Hydrogenase: Hydrides and Redox," F. Gloaguen, T. B. Rauchfuss Chem. Soc. Rev., 2009, 38, 100-108.
2008
"Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases", B. E. Barton, M. T. Olsen, T. B. Rauchfuss, J. Am. Chem. Soc., 2008, 130, 16834-16835.
"[Fe Fe]-Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes", Z. M. Heiden, G. Zampella, L. De Gioia, T. B. Rauchfuss, Angew. Chem. Int. Ed., 2008, 47, 9756-9759.
"Nitrosyl Derivatives of Diiron Dithiolates Related to FeFe Hydrogenase", M. T. Olsen, A. K. Justice, F. G. Gloaguen, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem. 2008, 47, 11816-11824.
"Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6 from CO-Free Iron Sources", P. I. Volkers, C. A. Boyke, J. Chen, T. B. Rauchfuss, C. M. Whaley, S. R. Wilson, H. Yao, Inorg. Chem. 2008, 47, 7001-7008.
"X-ray Photochemistry in Iron Complexes from Fe(0) to Fe(IV) – Can a Bug Become a Feature?" S. J. George, J. Fu, Y. Guo, O. B. Drury, S. Friedrich, T. B. Rauchfuss, P. I. Volkers, J. C. Peters, V. Scott, S. D. Brown, C. M. Thomas, S. P. Cramer, Inorg. Chim. Acta, 2008, 361, 1157-1165.
"Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the FeFe-Hydrogenase Active Site", M. T. Olsen, M. Bruschi, L. De Gioia, T. B. Rauchfuss, S. R. Wilson, J. Am Chem. Soc. 2008, 130, 12021-12030.
"Redox and Structural Properties of Models for the H ox State of the [FeFe]-Hydrogenase: Progress and Challenges", A. K. Justice, L. De Gioia, M. J. Nilges, T. B. Rauchfuss, S. R. Wilson, G. Zampella, Inorg. Chem., 2008, 47, 7405-7414.
"Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2 Production than the Isomeric Bridging Hydride", B. E. Barton, T. B. Rauchfuss, Inorg. Chem., 2008, 47, 2261-2263.
"Supramolecular Architectures Based on Organometallic Half-sandwich Complexes", T. B. Rauchfuss, K. Severin, in "Molecular Nanostructures" J. Atwood, J. Steed, eds. Wiley-VCH, 2008; 179-201.
"Desulfurization of Petroleum Streams Utilizing Multi-Ring Aromatic Alkali Metal Complex", M. Siskin, R. D. Myers, R. Beardon, T. B. Rauchfuss, U. S. Patent filed November, 2007, assigned to ExxonMobil.
"Expanded Cyanometallate Cages Derived from Dimetallic Dicyanide Building Blocks: {[Cp*Rh]4[Fe2(S2C3H6)(CN)2(CO)4]6}4- ", J. L. Boyer, T. B. Rauchfuss, S. R. Wilson, Comptes Rendus, 2008, 11, 922-925.
"Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity," Z. M. Heiden, B. J. Gorecki, T. B. Rauchfuss, Organometallics 2008, 28, 1542-1549.
"Diiron Dithiolato Carbonyls Related to HoxCO State of [FeFe]-Hydrogenase," A. K. Justice, M. A. Nilges, T. B. Rauchfuss, S. R. Wilson, L. De Gioia, G. Zampella, J. Am Chem.Soc. 2008, 130, 5293-5301.
"Characterization of the Fe Site in Methanothermobacter marburgensis Hydrogenase (mHmd) via Nuclear Resonant Vibrational Spectroscopy (NRVS)," Y. Guo, H. Wang, Y. Xiao, S. Vogt, R. K. Thauer, S. Shima, T. B. Rauchfuss, P. I. Volkers, E. Alp, W. Sturhahn, Y. Yoda, S. P. Cramer, Inorg. Chem., 2008, 47, 3969-3977.
"Coordination Chemistry of a Model for the GP Cofactor in the Hmd Hydrogenase: Hydrogen-Bonding and Hydrogen-Transfer Catalysis," A. M. Royer, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem., 2008, 46, 395-397.
"Desymmetrized Diiron Azadithiolates: A Step Toward Modeling the Fe-only Hydrogenases" J. L. Stanley, Z. M. Heiden, T. B. Rauchfuss, S. R. Wilson, L. De Gioia, G. Zampella, Organometallics 2008, 27, 119-125.
"Redox-Switched Oxidation of Dihydrogen using a Non-innocent Ligand," M. R. Ringenberg,S. L. Kokatam, Z. M. Heiden, T. B. Rauchfuss, J. Am. Chem. Soc, 2008, 130, 788-789.